I would think if a boiler explosion was to occur due to flooding it would have been during the rapid inundation of boiler room 6 while the boilers were at full pressure. I haven't read anything about such an explosion being reported. Once the boilers in the precceding boiler rooms had their fires drawn and pressure released I would think such an explosion would be even less likely.
I believe there was a great amount of steam inside the vessel when she exploded and broke apart. Wireless operator Harold Cottam said - "I was helping the Titanic to communicate.....He said he could not read signals because of the escape of steam and the air through the expansion joint, so I helped him with the communications.....The water rushing into the hollow of the ship was driving the air through the expansion joint....It would not be the noise only; it would be the trembling of the ship."
Harold Bride said - "The noise of escaping steam directly over our cabin caused a deal of trouble to Mr. Phillips in reading the replies to our distress call, and this I also reported to Captain Smith, who by some means managed to get it abated."
We don't know what the Captain did, but the steam might have been redirected using valves and pipes or allowed to build up in some other part of the vessel until it burst out, or possibly vented out by other means. Possibly a mechanical or human error caused a catastrophe inside.
In the final moments of the disaster the steam was still venting out / bursting out. Jack Thayer said - "The exhaust steam was still roaring. The lights were still strong. The band, with life preservers on, was still playing.......It was now about 2:15 am. We could see the water creeping up the deck, as the ship was going down by the head at a pretty fast rate. The water was right up to the bridge. There must have been over 60 feet of it on top of the bow. As the water gained headway along the deck, the crowd gradually moved with it, always pushing toward the floating stern and keeping in from the rail of the ship as far as they could. We were a mass of hopeless, dazed humanity, attempting, as the Almighty and Nature made us, to keep our final breath until the last possible moment. The roaring of the exhaust
steam suddenly stopped, making a great quietness, in spite of many mixed noises of hurrying human effort and anguish. As I recall it, the lights were still on, even then. There seemed to be quite a ruddy glare, but it was a murky light, with distant people and objects vaguely outlined. The stars were brilliant and the water oily. Occasionally there had been a muffled thud or deadened explosion within the ship. Now, without warning, she seemed to start forward, moving forward and into the water at an angle of about 15 degrees. This movement, with the water rushing up toward us was accompanied by a rumbling roar, mixed with more muffled explosions."
When the explosive sound was heard it was mixed with the sounds of steam exploding out.
Frank Osman said - "After she got to a certain angle she exploded, broke in halves, the after part came up right again....You could see the explosions by the smoke coming right up the funnels....It was all black; looked like as if it was lumps of coal, and all that. Pretty big lumps. Just after the explosion. Through the funnels.
Steam and very black smoke."
Jack Thayer saw the 2nd funnel fall over - "with a mass of sparks and
steam coming out of it. I saw the ship in a sort of a red glare, and it seemed to me that she broke in two just in front of the third funnel."
Mr. Hyman heard the hissing of steam as she exploded and broke apart. "There came a terrible explosion, and I could see men, women and pieces of the ship blown into the air from the after deck. Later I saw bodies partly blown to pieces floating around, and I am sure more than a hundred persons were blown off into the sea by that explosion. A
terrible hissing of steam began and the awful cry went on. I tried to close my ears, but there was some mysterious attraction and I had to hear that cry. The
hissing and screaming kept up, and finally the ship seemed to right itself."
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